滇东南都龙超大型锡锌多金属矿床黄铁矿LA-ICPMS微量元素组成研究     

刘仕玉  刘玉平  叶霖  王大鹏 《岩石学报》2021,37(4):1196-1212

滇东南马关都龙是一个以锡锌为主,共-伴生铟、铜、铅、钨、铁、银等多种元素的锡锌多金属超大型矿床。虽然前人从矿物学、矿床地球化学、年代学等不同角度开展了较多的研究,该矿床锡锌多金属矿化为燕山晚期岩浆热液活动的产物已是不争的事实,但关于该矿床是否存在热水沉积作用及其与锡锌多金属成矿作用的关系依然存在较大争议。本文选取都龙矿区广泛存在的黄铁矿作为主要研究对象,在矿相学基础上利用LA-ICPMS对不同阶段黄铁矿的微量元素组成开展了系统的研究。野外及显微鉴定结果表明,矿区存在四种类型(期次)的黄铁矿,即:鲕状黄铁矿Py1;穿切或交代Py1的细脉状黄铁矿Py2;与闪锌矿等硫化物共生的自形黄铁矿Py3;包裹早期黄铁矿或闪锌矿等硫化物的他形黄铁矿Py4。LA-ICPMS分析结果表明,该矿床黄铁矿中富集多种微量元素,其中Co、Ni、As、Ge等元素以类质同象的形式存在黄铁矿晶格中,而其余元素多以显微矿物包体形式赋存于黄铁矿中。上述四期黄铁矿微量元素组成存在较大差别,Py1相对富集Zn和As,而其余微量元素含量较低,Co与Ni含量较低,Co/Ni比值远低于1.00,其微量元素组成与典型沉积作用形成黄铁矿基本一致; Py2与Py1具有相似的微量元素组成特征,其Co/Ni比值接近Py1变化范围; Py3和Py4除富集Zn、As外,Mn、Co、Ni、Cu、Sb、Pb、Bi元素含量也相对较高,其Co/Ni比值相对较高,多大于1,与典型岩浆热液型黄铁矿微量元素组成相似,而与沉积型黄铁矿差异明显。结合各阶段黄铁矿产出地质特征,对比不同类型黄铁矿微量元素组成,本研究认为:Py1鲕状黄铁矿为热水沉积作用形成; Py2为Py1变质改造形成的细脉状黄铁矿,其微量元素继承了Py1; Py3为岩浆热液活动形成的自形黄铁矿; Py4为岩浆热液活动晚期形成的他形黄铁矿,Ag和Bi组成作为区分不同成因类型黄铁矿的化学指标的潜力。矿区早期沉积作用形成鲕状黄铁矿过程可能为后期成矿作用提供了部分硫源及少量Zn等成矿物质,海西-印支期区域变质改造作用对矿区成矿作用影响不大,而燕山晚期岩浆热液活动才是矿区锡多金属大规模成矿作用的主导因素。  相似文献   

下庄竹山下铀矿床黄铁矿元素地球化学特征及其表征意义     

刘文泉  江卫兵  李海东  李俊  梁园园 《铀矿地质》2021,(1):15-27

竹山下铀矿床是粤北下庄铀矿田内大型铀矿床之一,铀矿化类型为"交点"型和硅化带型。在详细的野外地质调查基础上,对竹山下铀矿床4种不同类型黄铁矿进行元素含量分析及硫同位素测试,结果表明:"交点"型矿石中黄铁矿相对富集Pb、 Cu、 Co、 As、 Ni、 Se、 Bi、 U、 Sb、 Zn等微量元素;"交点"型铀矿化形成于中深部高温环境,成矿热液具有地幔流体特征,成矿过程硫来源与该区花岗岩中黄铁矿的硫来源一致或者相似,花岗岩中的黄铁矿可能为该期成矿事件的产物;竹山下矿床在垂向上表现出越往深部硫逸度越低的特征;"交点"型和硅化带型中黄铁矿具有相似的微量元素配分曲线,表明二者具有相同的成矿热液来源,且与辉绿岩中黄铁矿配分曲线相似,表明该区成矿热液具有深源性。  相似文献   

微波消解-电感耦合等离子体质谱法测定土壤中稀土元素条件优化     

张祎玮  蒋俊平  李浩  沈讷敏 《岩石矿物学杂志》2021,40(3):605-613

稀土元素因其用途广泛,已经得到了越来越多的关注,被应用于各个行业。研究表明,稀土元素对作物的光合作用、产量、抗逆、品质、发育和养分吸收等具有重要作用。作物中的稀土元素主要来自对土壤中稀土元素的吸收,因此,有效分解并快速测定土壤中的稀土元素,可以合理指导稀土元素的施用,对作物的生长和土壤的营养状况具有重要作用。本文比较了敞口酸溶、密闭消解、微波消解和碱熔等4种消解样品前处理方法,最终确定采用微波消解-电感耦合等离子体质谱法(ICP-MS)快速测定土壤中的稀土元素,并通过优化微波消解的条件,选择合适的试剂用量、消解温度、消解时间,对方法的检出限、精密度、准确度、回收率进行了实验,结果显示其测定均值与标准值基本吻合,相对误差(RE)绝对值为0.16%～3.39%,精密度为0.27%～5.09%,均小于10%,加标回收率为93.1%～106.0%。该方法准确度高、稳定性好,可以有效地应用于土壤中稀土元素的分析测定。  相似文献   

浙江省衢州市上方镇重钙方解石矿工艺指标影响因素     

叶皓玮  刘成东  赵严  万建军  张辉  张勇  周万蓬 《矿物岩石地球化学通报》2021,40(2):371-381

重质碳酸钙的白度和色相值(Lab)是最重要的工业指标,但影响因素尚不清楚。本文通过扫描电镜、粉晶X射线衍射(XRD)和电感耦合等离子体发射光谱(ICP-OES)等分析手段,对浙江衢州上方镇的重钙方解矿石进行了研究,以期阐明重质碳酸钙白度和色相的影响因素。结果表明,矿石随研磨粒度的减小白度逐渐增加,在100~400目,白度呈快速上升趋势,超过400目,白度的上升趋势减缓,直至几乎不变。相较于青相矿石,红相矿石的方解石结晶程度高、颗粒大且均匀,杂质较少,化学成分较纯。而Fe3+含量与重钙产品白度和L值呈负相关,与a、b值呈正相关关系。综合研究认为,致色元素(Fe)含量的高低和原矿石的杂质含量、结晶程度均可能为重钙色相差异的主要原因,建议在方解石矿工业勘查中将白度指标测试的粒径统一为400目(38μm)。  相似文献   

东昆仑造山带低山头花岗岩体岩石地球化学特征及其地质意义     

邓红宾  李培龙  魏华财  何文劲  杨鹏涛  李宁  唐华 《吉林大学学报(地球科学版)》2021,51(3):767-782

低山头一带花岗岩体归属东昆仑弧盆系北昆仑岩浆弧带,位于东昆仑成矿带伯喀里克—香日德成矿亚带东昆仑造山带中段,岩石类型主要为石英闪长岩、正长花岗岩及二长花岗岩。为了加强该地区花岗岩体岩石地球化学与成岩成矿背景探讨,对花岗岩体开展了主量元素、微量元素及矿质元素研究。主量元素组成上,石英闪长岩具中硅（57.64%和58.47%）、富钠（Na₂O/K₂O均为2.57）特点,正长花岗岩具高硅（75.45%~75.99%）、富钾（Na₂O/K₂O为0.74~0.94）特点,二长花岗岩具高硅（66.80%~73.45%）、富钠（Na₂O/K₂O为1.50~2.13）特点;花岗岩体铝饱和指数A/CNK<1,为准铝质岩浆岩;碱饱和指数NK/A集中在0.26~0.69之间,属钙碱性岩石;里特曼组合指数σ₄₃在1.18~2.31之间,属钙碱性类型。花岗岩体轻稀土元素相对重稀土元素富集,岩浆分异特征明显,大离子亲石元素（LILE）富集Rb、K、Ba、Th、Sr、Nd,仅正长花岗岩Sr亏损,高场强元素（HFSE）富集Zr、Hf、Ce,而Nb、P、Ti明显亏损,源区物质为壳幔混合物质,属挤压应力环境中同碰撞I型花岗岩。在岩体实测剖面中获得11种元素分析数据,与青海全省、东昆仑成矿带及其亚成矿带平均元素丰度值进行对比,初步划分不同岩性、不同类型、不同时代花岗岩,以及富集的含矿元素为Au、Zn、Y、Pb等。与区域有成矿事实且为I型花岗岩成因进行对比,认为研究区有较好的找矿前景。  相似文献   

Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon): Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints          下载免费PDF全文

Yemeli Elida Joelle  Temgoua Emile  Kengni Lucas  Ambrosi Jean-Paul  Momo-nouazi Mathieu  Silatsa-Tedou Francis Brice  Wamba Franck Robean  Tchakam-Kamtchueng Brice 《地下水科学与工程》2021,9(3):212-224

This study focuses on the sources of alkali and alkaline-earth elements based on the geochemistry of groundwater and surface water in Dschang concerning environmental and anthropogenic constraints. A comprehensive set of 50 samples from groundwater and surface water were analyzed by ICPMS and processed by spatial interpolation in a GIS environment. The results highlight a geochemical anomaly at the center of the densely inhabited area subject to a profusion of open dumps discharges. This anomaly with the highest spatial contents of Be(Cs, Rb, Mg) suggests an anthropogenic source that demarcates with the lowest alkali and alkaline-earth elements on the peripheral area of Dschang. Other findings include lithological constraints with volcanic rocks being the main source compared to granitoid.The study points out good correlations between Be, Cs, Rb and Mg spatial distributions and physicochemical parameters of waters(K, EC, TDS), and inversely with the lowest p H. p H is established as the most functioning physico-chemical constraint of alkali and alkaline-earth mobility in Dschang. The p H lowest values within the geochemical anomaly also highlight the impact of human activities on water acidity, which later enhance elements mobility and enrichment. Despite low elements contents relative to WHO standards, our findings point out an example of anthropogenic impact on water geochemistry linked to solid waste pollution; it also demonstrates significant anthropogenic changes of environmental physicochemical parameters of prime importance in the mobility and distribution of elements in the study area.Similar assessments should be extended in major towns in Cameroon.  相似文献   

Pyroxenite xenoliths and clinopyroxene megacrysts from the Cenozoic Jbel Saghro Volcanic Field (Anti-Atlas,Morocco): Petrography,mineral chemistry and equilibration conditions     

《Chemie der Erde / Geochemistry》2021,81(1):125694

A suite of mafic pyroxenite xenoliths and clinopyroxene megacrysts was brought to the surface by Cenozoic nephelinites of the Jbel Saghro Volcanic Field (Anti-Atlas, Morocco). The large population of samples was subdivided into five groups: (i) clinopyroxenites sensu stricto; (ii) olivine clinopyroxenites; (iii) mica-bearing clinopyroxenites; (iv) kaersutite-bearing clinopyroxenites; (v) clinopyroxene megacrysts. These xenoliths display a cumulate texture (adcumulate, heteradcumulate with poikilitic clinopyroxene including olivine). The clinopyroxenes have the composition of augite and show an appreciable variation of MgO (7.02–14.80 wt.%), TiO₂ (0.58–5.76 wt.%) and Al₂O₃ (2.81–12.38 wt.%) contents in grains. The clinopyroxenes are characterized by convex upward chondrite-normalized REE patterns, they display very similar trace element compositions with low contents of incompatible elements such as Rb (0−0.9 ppm), Ba (0.1–8.3 ppm), Th (0.1−0.3 ppm), U (0.01−0.04 ppm) and Nb (1.3–3.2 ppm). REE contents of the calculated melts in equilibrium with the clinopyroxene megacrysts and clinopyroxene from pyroxenite xenoliths are similar to those of the nephelinites exposed in Jbel Saghro. Crystallization temperatures of pyroxenite xenoliths and clinopyroxene megacrysts range from 950 °C to 1150 °C. Clinopyroxene barometry yielded pressure of crystallization ranging from 0.4 to 0.8 GPa for pyroxenite xenoliths and 0.3 to 0.7 GPa for clinopyroxene megacrysts. This pressure range is in agreement with pyroxenite xenoliths and clinopyroxene megacrysts being crystallized from their parental melts at the lower and upper crust.  相似文献   

Geochemical constraints on the distribution of trace elements and volatiles in fluorapatite from the Panasqueira tin-tungsten deposit (Portugal)     

《Chemie der Erde / Geochemistry》2021,81(2):125765

A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap_2core and Ap_2rim, respectively), which grew on a previous, euhedral crystal (Ap₁). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap_2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap_2core and older crystal Ap₁. Furthermore, the rim Ap_2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap₁, Ap_2core and Ap_2rim, whereas Cl is below the EPMA detection limit. The Ap_2rim was the only part of the investigated material containing OH and CO₃, which were observed in the Raman spectra. Furthermore, part of the crystal Ap_2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap₁ and Ap_2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap_2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit.  相似文献   

Chemical oceanographic influences on sediment accumulations of a carbonate ramp: Holocene Yucatan Shelf,Mexico     

Eugene C. Rankey  Rodrigo Garza‐Perez  Hassan A. Eltom 《Sedimentology》2021,68(1):324-351

Global controls on the oceanographic influences on the nature of carbonate factories are broadly understood. The details of the influences of changes in temperature and nutrients across individual carbonate shelves are less well constrained, however. This study explores spatial and temporal variations in chemical oceanography along and across the Yucatan Shelf, a modern carbonate ramp, and how these factors relate to variable bottom character, sediment and sediment geochemistry. In‐situ sensors and remote‐sensing data indicate the sporadic presence of cool, upwelled water with low dissolved oxygen and elevated Chlorophyll‐a. This current‐driven, westward flow of upwelled water is most evident in a zone just offshore of the northern peninsular shoreline, but its influence wanes ca 75 km offshore and as the shore turns southward. The impacts of this water mass include a transitional photozoan–heterozoan assemblage with biosiliceous components, relict grains and common thin Holocene sediment accumulations nearshore; further offshore are coralgal reefs and expansive sand plains. Geochemical proxies of bulk sediment, including high δ¹⁸O and elevated HREE/LREE (heavy rare‐earth element/light rare‐earth element) ratios near, and downcurrent of, the upwelling source, are interpreted to represent the signal of nearshore, westward movement of the cool and nutrient‐rich, upwelled water. Collectively, these data emphasize how local processes such as upwelling and longshore transport can variably influence carbonate sediment accumulations and their geochemical signatures, both along and across individual shelves. These data and insights provide an analogue for the influences of spatial variability of water masses in the geological record, and for accurate interpretation of stratigraphic changes of sedimentary and geochemical proxy data in carbonate archives.  相似文献   

2016—2017年贵州大雾时空分布及气象要素演变分析          下载免费PDF全文

胡跃文  秦杰  苏静文  牛迪宇  吉廷艳 《气象》2019,45(5):659-666

利用2016—2017年自动站逐小时观测资料,统计分析了贵州大雾天气的时空分布特征;同时,结合天气图资料分析筛选了锋面大雾个例31 d和辐射大雾个例17 d,对比分析大雾生消过程中风、温、湿等气象要素演变特点。结果表明：(1)贵州大雾在秋末到初春较为频发;一天中夜间02—09时是大雾频发时段,07时达到峰值。(2)贵州自西向东有4个多雾区,分别为西南部区域、中部区域、东部边缘区域和北部局部区域。(3)锋面大雾主要出现在贵州中西部,范围最广时可达20个县站左右,持续时长可达10~13 h,单站可持续60 h以上。辐射大雾以贵州中东部地区出现较多,范围最广时可接近40个县站,远比锋面大雾范围广,持续时间相对较短。(4)大雾期间,10 min平均风速为0~3 m?s-1,相对湿度为97%~100%,温度露点差为0~0.5℃;辐射大雾初期或形成前气温呈下降状态,消散期升温较明显,地气温差呈现由负到正或由低到高的变化趋势,反映出近地层大气由较为稳定的逆温环境向不稳定环境变化的过程;锋面大雾初期的降温和后期的升温现象并不突出,地气温差也没有特定的变化规律,仅有部分个例与锋面大雾情况一致。  相似文献